Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography

E. Muzenda, M. Belaid, A. Arrowsmith, N. Ashton

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Stable organic oils, may play a significant role in the effective removal of VOC from gas streams by gas absorption. A gas liquid chromatographic (GLC) technique was proposed for the measurement of infinite dilution activity coefficients for the 13 organic compounds in poly(dimethylsiloxane) (PDMS) at 303 K. Static determined activity coefficients using shaker flasks were also reported and compared with the GLC results. The values obtained compared very well with those reported previously for other PDMS used as stationary liquids in analytical GLC and those obtained by these authors using group contribution methods. The successful comparison gave an indication of the GLC as a rapid, simple, and accurate method for studying the thermodynamics of the interaction of a volatile solute with a non volatile solvent. The greatest deviation from ideal behavior was usually exhibited in the dilute regions. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montréal, Quebec, Canada 8/23-27/2009).

Original languageEnglish
Title of host publication8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
Publication statusPublished - 2009
Event8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering - Montreal, QC, Canada
Duration: Aug 23 2009Aug 27 2009

Other

Other8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
CountryCanada
CityMontreal, QC
Period8/23/098/27/09

Fingerprint

Volatile Organic Compounds
Polydimethylsiloxane
Volatile organic compounds
Thermodynamics
Gases
Liquids
Activity coefficients
Gas absorption
Chemical Engineering
Chemical engineering
Organic compounds
Quebec
Dilution
Oils
Canada
baysilon

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Chemical Health and Safety
  • Process Chemistry and Technology
  • Renewable Energy, Sustainability and the Environment

Cite this

Muzenda, E., Belaid, M., Arrowsmith, A., & Ashton, N. (2009). Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. In 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
Muzenda, E. ; Belaid, M. ; Arrowsmith, A. ; Ashton, N. / Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 2009.
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abstract = "Stable organic oils, may play a significant role in the effective removal of VOC from gas streams by gas absorption. A gas liquid chromatographic (GLC) technique was proposed for the measurement of infinite dilution activity coefficients for the 13 organic compounds in poly(dimethylsiloxane) (PDMS) at 303 K. Static determined activity coefficients using shaker flasks were also reported and compared with the GLC results. The values obtained compared very well with those reported previously for other PDMS used as stationary liquids in analytical GLC and those obtained by these authors using group contribution methods. The successful comparison gave an indication of the GLC as a rapid, simple, and accurate method for studying the thermodynamics of the interaction of a volatile solute with a non volatile solvent. The greatest deviation from ideal behavior was usually exhibited in the dilute regions. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montr{\'e}al, Quebec, Canada 8/23-27/2009).",
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Muzenda, E, Belaid, M, Arrowsmith, A & Ashton, N 2009, Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. in 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering, Montreal, QC, Canada, 8/23/09.

Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. / Muzenda, E.; Belaid, M.; Arrowsmith, A.; Ashton, N.

8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 2009.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Muzenda E, Belaid M, Arrowsmith A, Ashton N. Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. In 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 2009