Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography

E. Muzenda, M. Belaid, A. Arrowsmith, N. Ashton

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    Stable organic oils, may play a significant role in the effective removal of VOC from gas streams by gas absorption. A gas liquid chromatographic (GLC) technique was proposed for the measurement of infinite dilution activity coefficients for the 13 organic compounds in poly(dimethylsiloxane) (PDMS) at 303 K. Static determined activity coefficients using shaker flasks were also reported and compared with the GLC results. The values obtained compared very well with those reported previously for other PDMS used as stationary liquids in analytical GLC and those obtained by these authors using group contribution methods. The successful comparison gave an indication of the GLC as a rapid, simple, and accurate method for studying the thermodynamics of the interaction of a volatile solute with a non volatile solvent. The greatest deviation from ideal behavior was usually exhibited in the dilute regions. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montréal, Quebec, Canada 8/23-27/2009).

    Original languageEnglish
    Title of host publication8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
    Publication statusPublished - 2009
    Event8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering - Montreal, QC, Canada
    Duration: Aug 23 2009Aug 27 2009

    Other

    Other8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
    CountryCanada
    CityMontreal, QC
    Period8/23/098/27/09

    Fingerprint

    Volatile Organic Compounds
    Polydimethylsiloxane
    Volatile organic compounds
    Thermodynamics
    Gases
    Liquids
    Activity coefficients
    Gas absorption
    Chemical Engineering
    Chemical engineering
    Organic compounds
    Quebec
    Dilution
    Oils
    Canada
    baysilon

    All Science Journal Classification (ASJC) codes

    • Biotechnology
    • Chemical Health and Safety
    • Process Chemistry and Technology
    • Renewable Energy, Sustainability and the Environment

    Cite this

    Muzenda, E., Belaid, M., Arrowsmith, A., & Ashton, N. (2009). Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. In 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
    Muzenda, E. ; Belaid, M. ; Arrowsmith, A. ; Ashton, N. / Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 2009.
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    abstract = "Stable organic oils, may play a significant role in the effective removal of VOC from gas streams by gas absorption. A gas liquid chromatographic (GLC) technique was proposed for the measurement of infinite dilution activity coefficients for the 13 organic compounds in poly(dimethylsiloxane) (PDMS) at 303 K. Static determined activity coefficients using shaker flasks were also reported and compared with the GLC results. The values obtained compared very well with those reported previously for other PDMS used as stationary liquids in analytical GLC and those obtained by these authors using group contribution methods. The successful comparison gave an indication of the GLC as a rapid, simple, and accurate method for studying the thermodynamics of the interaction of a volatile solute with a non volatile solvent. The greatest deviation from ideal behavior was usually exhibited in the dilute regions. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montr{\'e}al, Quebec, Canada 8/23-27/2009).",
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    Muzenda, E, Belaid, M, Arrowsmith, A & Ashton, N 2009, Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. in 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering, Montreal, QC, Canada, 8/23/09.

    Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. / Muzenda, E.; Belaid, M.; Arrowsmith, A.; Ashton, N.

    8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 2009.

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

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    AU - Muzenda, E.

    AU - Belaid, M.

    AU - Arrowsmith, A.

    AU - Ashton, N.

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    N2 - Stable organic oils, may play a significant role in the effective removal of VOC from gas streams by gas absorption. A gas liquid chromatographic (GLC) technique was proposed for the measurement of infinite dilution activity coefficients for the 13 organic compounds in poly(dimethylsiloxane) (PDMS) at 303 K. Static determined activity coefficients using shaker flasks were also reported and compared with the GLC results. The values obtained compared very well with those reported previously for other PDMS used as stationary liquids in analytical GLC and those obtained by these authors using group contribution methods. The successful comparison gave an indication of the GLC as a rapid, simple, and accurate method for studying the thermodynamics of the interaction of a volatile solute with a non volatile solvent. The greatest deviation from ideal behavior was usually exhibited in the dilute regions. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montréal, Quebec, Canada 8/23-27/2009).

    AB - Stable organic oils, may play a significant role in the effective removal of VOC from gas streams by gas absorption. A gas liquid chromatographic (GLC) technique was proposed for the measurement of infinite dilution activity coefficients for the 13 organic compounds in poly(dimethylsiloxane) (PDMS) at 303 K. Static determined activity coefficients using shaker flasks were also reported and compared with the GLC results. The values obtained compared very well with those reported previously for other PDMS used as stationary liquids in analytical GLC and those obtained by these authors using group contribution methods. The successful comparison gave an indication of the GLC as a rapid, simple, and accurate method for studying the thermodynamics of the interaction of a volatile solute with a non volatile solvent. The greatest deviation from ideal behavior was usually exhibited in the dilute regions. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montréal, Quebec, Canada 8/23-27/2009).

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    Muzenda E, Belaid M, Arrowsmith A, Ashton N. Thermodynamic data for volatile organic compounds in poly(dimethylsiloxane) by gas liquid chrmatography. In 8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering. 2009