Synthesis of boron suboxide (B6O) with alkaline earth metal oxide materials with improved properties

E.N. Ogunmuyiwa, O.T. Johnson, I. Sigalas

Research output: Contribution to journalArticle

Abstract

The pure boron suboxide (B6O) powder admixed with 1.08 vol% of MgO, CaO, and CaCO3 (corresponding to 1.5, 1.4, and 0.7 wt%, respectively) were synthesized by hot-pressing and the mechanical properties were evaluated. Pure B6O powders were sintered at a temperature of 1900°C, while the B6O-alkaline earth metal oxide admixed powders were sintered at a temperature of 1850°C. All sintering was done under an applied load of 80 MPa in an argon environment. The microstructures and phase analyses were studied by scanning electron microscopy and X-ray diffraction techniques, respectively. The addition of the alkaline earth metal oxide additives resulted in the formation of boride and borate phases, depending on the oxide used. The mechanical properties of the hot-pressed materials were characterized based on their density, hardness, and fracture toughness. Between 95 and 98% of the theoretical densities were achieved and the result indicate a good combination of hardness (between 31.6 and 32.1 GPa) and fracture toughness (between 6.1 and 6.8 MPa.m0.5) in the B6O-alkaline earth metal oxide materials. The introduction of the additive enhances the fracture toughness of the pure B6O-materials, while the fracture mode observed in the sintered materials is mainly transgranular.
Original languageEnglish
Pages (from-to)1-8
Number of pages8
JournalParticulate Science and Technology
DOIs
Publication statusPublished - 2017

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Alkaline Earth Metals
Alkaline earth metals
Boron
Oxides
Powders
Fracture toughness
Boron Compounds
Hardness
Mechanical properties
Borates
Borides
Argon
Hot pressing
Sintering
X ray diffraction
Temperature
Microstructure
Scanning electron microscopy

Cite this

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title = "Synthesis of boron suboxide (B6O) with alkaline earth metal oxide materials with improved properties",
abstract = "The pure boron suboxide (B6O) powder admixed with 1.08 vol{\%} of MgO, CaO, and CaCO3 (corresponding to 1.5, 1.4, and 0.7 wt{\%}, respectively) were synthesized by hot-pressing and the mechanical properties were evaluated. Pure B6O powders were sintered at a temperature of 1900°C, while the B6O-alkaline earth metal oxide admixed powders were sintered at a temperature of 1850°C. All sintering was done under an applied load of 80 MPa in an argon environment. The microstructures and phase analyses were studied by scanning electron microscopy and X-ray diffraction techniques, respectively. The addition of the alkaline earth metal oxide additives resulted in the formation of boride and borate phases, depending on the oxide used. The mechanical properties of the hot-pressed materials were characterized based on their density, hardness, and fracture toughness. Between 95 and 98{\%} of the theoretical densities were achieved and the result indicate a good combination of hardness (between 31.6 and 32.1 GPa) and fracture toughness (between 6.1 and 6.8 MPa.m0.5) in the B6O-alkaline earth metal oxide materials. The introduction of the additive enhances the fracture toughness of the pure B6O-materials, while the fracture mode observed in the sintered materials is mainly transgranular.",
author = "E.N. Ogunmuyiwa and O.T. Johnson and I. Sigalas",
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Synthesis of boron suboxide (B6O) with alkaline earth metal oxide materials with improved properties. / Ogunmuyiwa, E.N.; Johnson, O.T.; Sigalas, I.

In: Particulate Science and Technology, 2017, p. 1-8.

Research output: Contribution to journalArticle

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PY - 2017

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AB - The pure boron suboxide (B6O) powder admixed with 1.08 vol% of MgO, CaO, and CaCO3 (corresponding to 1.5, 1.4, and 0.7 wt%, respectively) were synthesized by hot-pressing and the mechanical properties were evaluated. Pure B6O powders were sintered at a temperature of 1900°C, while the B6O-alkaline earth metal oxide admixed powders were sintered at a temperature of 1850°C. All sintering was done under an applied load of 80 MPa in an argon environment. The microstructures and phase analyses were studied by scanning electron microscopy and X-ray diffraction techniques, respectively. The addition of the alkaline earth metal oxide additives resulted in the formation of boride and borate phases, depending on the oxide used. The mechanical properties of the hot-pressed materials were characterized based on their density, hardness, and fracture toughness. Between 95 and 98% of the theoretical densities were achieved and the result indicate a good combination of hardness (between 31.6 and 32.1 GPa) and fracture toughness (between 6.1 and 6.8 MPa.m0.5) in the B6O-alkaline earth metal oxide materials. The introduction of the additive enhances the fracture toughness of the pure B6O-materials, while the fracture mode observed in the sintered materials is mainly transgranular.

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