Steady state model of the electrochemical process of brine electrolysis in denora amalgam reactors

Llviu Oniciu, Şerban Agachi, Julia Bugan, Árpád Imre-Lucaci

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The present paper describes the mathematical model of the process, using electrochemical, thermodynamic and kinetic equations. The mathematical model of the cell is composed of mass, heat and voltage balance equations, taking into account significant facts such as the developing of the gas bubbles, the changing of the flowing profile of the amalgam, the mixing in the cell and others. The program computes the parameters along the cell (concentrations, temperatures), the interelectrode voltage on each anodic line and their components. A fairly good match of the computed data was observed with the experimental ones. The model can be used in Optimisation and Expert System control of the electrolysis process.

Original languageEnglish
Pages (from-to)81-89
Number of pages9
JournalHungarian Journal of Industrial Chemistry
Volume25
Issue number2
Publication statusPublished - Jan 1 1997

Fingerprint

Mercury amalgams
Electrolysis
Mathematical models
Electric potential
Expert systems
Gases
Thermodynamics
Kinetics
Temperature
brine
Hot Temperature

All Science Journal Classification (ASJC) codes

  • Chemistry (miscellaneous)
  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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Steady state model of the electrochemical process of brine electrolysis in denora amalgam reactors. / Oniciu, Llviu; Agachi, Şerban; Bugan, Julia; Imre-Lucaci, Árpád.

In: Hungarian Journal of Industrial Chemistry, Vol. 25, No. 2, 01.01.1997, p. 81-89.

Research output: Contribution to journalArticle

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