Removal of multilan red and multi-active blue dyes from aqueous solution by adsorption and oxidation techniques: Equilibrium, kinetics and thermodynamic studies

Jacob Kitinya, Maurice S. Onyango, Aoyi Ochieng

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Abstract

This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multiactive blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than CTAB-modified zeolite for both dyes. Acidic pH (pH 2) was found favourable for the removal of both dyes from aqueous solution. The equilibrium data was well described by Freundlich and Langmuir isotherm models in that order. The maximum adsorption capacity of HDTMA-modified zeolite was found to be 476.19 mg g-1 for MActB and 1000 mg g-1 for MLR dye. The sorption kinetics followed pseudo second order and Elovich mechanisms. The thermodynamic studies showed that the adsorption of MActB dye onto HDTMA-modified zeolite is endothermic in nature whereas the adsorption of MLR is temperature-independent. The ΔH°, ΔS° and ΔG° in the sorption of MActB dye was 27.1 kJ mol-1, 52.54 J mol-1 K-1 and 42.8 kJ mol-1, respectively. The low value of ΔH° (< 40 kJ mol-1) suggests that the MActB dye sorption occurred through a physical means. Further, the Fenton's oxidation was able to achieve dye removal efficiency of 25-45 %. The combination of adsorption and Fenton oxidation significantly enhanced the dye removal efficiency to a maximum of 95 %, demonstrating its potential application in the treatment of textile dye effluents.
Original languageEnglish
Pages (from-to)2731-2743
Number of pages13
JournalEnvironmental Engineering and Management Journal
Volume16
Issue number12
Publication statusPublished - Dec 2017

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dye
aqueous solution
Dyes
thermodynamics
Thermodynamics
adsorption
Adsorption
oxidation
kinetics
Oxidation
Kinetics
zeolite
bromide
Sorption
sorption
removal
Adsorbents
surfactant
Isotherms
Effluents

Cite this

@article{546741dc26d346848590b0a9a6e659fd,
title = "Removal of multilan red and multi-active blue dyes from aqueous solution by adsorption and oxidation techniques: Equilibrium, kinetics and thermodynamic studies",
abstract = "This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multiactive blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than CTAB-modified zeolite for both dyes. Acidic pH (pH 2) was found favourable for the removal of both dyes from aqueous solution. The equilibrium data was well described by Freundlich and Langmuir isotherm models in that order. The maximum adsorption capacity of HDTMA-modified zeolite was found to be 476.19 mg g-1 for MActB and 1000 mg g-1 for MLR dye. The sorption kinetics followed pseudo second order and Elovich mechanisms. The thermodynamic studies showed that the adsorption of MActB dye onto HDTMA-modified zeolite is endothermic in nature whereas the adsorption of MLR is temperature-independent. The ΔH°, ΔS° and ΔG° in the sorption of MActB dye was 27.1 kJ mol-1, 52.54 J mol-1 K-1 and 42.8 kJ mol-1, respectively. The low value of ΔH° (< 40 kJ mol-1) suggests that the MActB dye sorption occurred through a physical means. Further, the Fenton's oxidation was able to achieve dye removal efficiency of 25-45 {\%}. The combination of adsorption and Fenton oxidation significantly enhanced the dye removal efficiency to a maximum of 95 {\%}, demonstrating its potential application in the treatment of textile dye effluents.",
author = "Jacob Kitinya and Onyango, {Maurice S.} and Aoyi Ochieng",
year = "2017",
month = "12",
language = "English",
volume = "16",
pages = "2731--2743",
journal = "Environmental Engineering and Management Journal",
issn = "1582-9596",
publisher = "Gh. Asachi Technical University of Iasi",
number = "12",

}

TY - JOUR

T1 - Removal of multilan red and multi-active blue dyes from aqueous solution by adsorption and oxidation techniques

T2 - Equilibrium, kinetics and thermodynamic studies

AU - Kitinya, Jacob

AU - Onyango, Maurice S.

AU - Ochieng, Aoyi

PY - 2017/12

Y1 - 2017/12

N2 - This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multiactive blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than CTAB-modified zeolite for both dyes. Acidic pH (pH 2) was found favourable for the removal of both dyes from aqueous solution. The equilibrium data was well described by Freundlich and Langmuir isotherm models in that order. The maximum adsorption capacity of HDTMA-modified zeolite was found to be 476.19 mg g-1 for MActB and 1000 mg g-1 for MLR dye. The sorption kinetics followed pseudo second order and Elovich mechanisms. The thermodynamic studies showed that the adsorption of MActB dye onto HDTMA-modified zeolite is endothermic in nature whereas the adsorption of MLR is temperature-independent. The ΔH°, ΔS° and ΔG° in the sorption of MActB dye was 27.1 kJ mol-1, 52.54 J mol-1 K-1 and 42.8 kJ mol-1, respectively. The low value of ΔH° (< 40 kJ mol-1) suggests that the MActB dye sorption occurred through a physical means. Further, the Fenton's oxidation was able to achieve dye removal efficiency of 25-45 %. The combination of adsorption and Fenton oxidation significantly enhanced the dye removal efficiency to a maximum of 95 %, demonstrating its potential application in the treatment of textile dye effluents.

AB - This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multiactive blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than CTAB-modified zeolite for both dyes. Acidic pH (pH 2) was found favourable for the removal of both dyes from aqueous solution. The equilibrium data was well described by Freundlich and Langmuir isotherm models in that order. The maximum adsorption capacity of HDTMA-modified zeolite was found to be 476.19 mg g-1 for MActB and 1000 mg g-1 for MLR dye. The sorption kinetics followed pseudo second order and Elovich mechanisms. The thermodynamic studies showed that the adsorption of MActB dye onto HDTMA-modified zeolite is endothermic in nature whereas the adsorption of MLR is temperature-independent. The ΔH°, ΔS° and ΔG° in the sorption of MActB dye was 27.1 kJ mol-1, 52.54 J mol-1 K-1 and 42.8 kJ mol-1, respectively. The low value of ΔH° (< 40 kJ mol-1) suggests that the MActB dye sorption occurred through a physical means. Further, the Fenton's oxidation was able to achieve dye removal efficiency of 25-45 %. The combination of adsorption and Fenton oxidation significantly enhanced the dye removal efficiency to a maximum of 95 %, demonstrating its potential application in the treatment of textile dye effluents.

M3 - Article

VL - 16

SP - 2731

EP - 2743

JO - Environmental Engineering and Management Journal

JF - Environmental Engineering and Management Journal

SN - 1582-9596

IS - 12

ER -