Phase equilibrium of volatile organic compounds in polymeric solvents using group contribution methods

Research output: Contribution to journalArticle

Abstract

Group contribution methods such as the UNIFAC are of major interest to researchers and engineers involved synthesis, feasibility studies, design and optimization of separation processes as well as other applications of industrial use. Reliable knowledge of the phase equilibrium behavior is crucial for the prediction of the fate of the chemical in the environment and other applications. The objective of this study was to predict the solubility of selected volatile organic compounds (VOCs) in glycol polymers and biodiesel. Measurements can be expensive and time consuming, hence the need for thermodynamic models. The results obtained in this study for the infinite dilution activity coefficients compare very well those published in literature obtained through measurements. It is suggested that in preliminary design or feasibility studies of absorption systems for the abatement of volatile organic compounds, prediction procedures should be implemented while accurate fluid phase equilibrium data should be obtained from experiment.

Original languageEnglish
Pages (from-to)242-247
Number of pages6
JournalWorld Academy of Science, Engineering and Technology
Volume70
Publication statusPublished - Sep 1 2010

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All Science Journal Classification (ASJC) codes

  • Engineering(all)

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