Investigating the synergy of integrated anaerobic digestion and photodegradation using hybrid photocatalyst for molasses wastewater treatment

Janet Mabuza, Benton Otieno, Seth Apollo, Boitumelo Matshediso, Aoyi Ochieng

Research output: Contribution to journalArticle

Abstract

Anaerobic digestion (AD) can remove the high organic load of molasses wastewater (MWW), but is ineffective in removing the characteristic dark brown colour caused by biorecalcitrant melanoidin. Ultraviolet (UV) photodegradation, can mineralise the biorecalcitrants leading to complete colour removal, but with a high-energy input and low organic load removal. This study investigated the plausibility of integrating the two processes for organic load and colour reductions. Desk scale AD and photodegradation processes were carried out in batch reactors. A hybrid photocatalyst consisting of titanium dioxide (TiO2) and zinc oxide (ZnO) was used for photocatalytic degradation. Biodegradation at thermophilic conditions in the bioreactor achieved high total organic carbon (TOC) and chemical oxygen demand (COD) reductions of 80 and 90%, respectively, but with an increased colour intensity. Contrastingly, UV photodegradation achieved a high colour reduction of 92% with an insignificant 6% TOC reduction, after 30 min of irradiation. During photodegradation, the mineralisation of the biorecalcitrant organic compounds led to the colour disappearance. The energy required for the TOC reduction was 40-fold higher than that required for the colour reduction in the same irradiation period, suggesting that the UV process was only suitable for colour reduction. Therefore, there is a possible synergy when the two processes are integrated, with AD preceding UV, where AD removes the high COD/TOC while UV removes the recalcitrant colour at a reduced cost.
Original languageEnglish
Number of pages10
JournalEuro-Mediterranean Journal for Environmental Integration
Volume2
DOIs
Publication statusPublished - 2017

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photodegradation
total organic carbon
chemical oxygen demand
irradiation
anaerobic digestion
wastewater treatment
bioreactor
energy
organic compound
biodegradation
zinc
oxide
mineralization
fold
wastewater
degradation
cost

Cite this

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title = "Investigating the synergy of integrated anaerobic digestion and photodegradation using hybrid photocatalyst for molasses wastewater treatment",
abstract = "Anaerobic digestion (AD) can remove the high organic load of molasses wastewater (MWW), but is ineffective in removing the characteristic dark brown colour caused by biorecalcitrant melanoidin. Ultraviolet (UV) photodegradation, can mineralise the biorecalcitrants leading to complete colour removal, but with a high-energy input and low organic load removal. This study investigated the plausibility of integrating the two processes for organic load and colour reductions. Desk scale AD and photodegradation processes were carried out in batch reactors. A hybrid photocatalyst consisting of titanium dioxide (TiO2) and zinc oxide (ZnO) was used for photocatalytic degradation. Biodegradation at thermophilic conditions in the bioreactor achieved high total organic carbon (TOC) and chemical oxygen demand (COD) reductions of 80 and 90{\%}, respectively, but with an increased colour intensity. Contrastingly, UV photodegradation achieved a high colour reduction of 92{\%} with an insignificant 6{\%} TOC reduction, after 30 min of irradiation. During photodegradation, the mineralisation of the biorecalcitrant organic compounds led to the colour disappearance. The energy required for the TOC reduction was 40-fold higher than that required for the colour reduction in the same irradiation period, suggesting that the UV process was only suitable for colour reduction. Therefore, there is a possible synergy when the two processes are integrated, with AD preceding UV, where AD removes the high COD/TOC while UV removes the recalcitrant colour at a reduced cost.",
author = "Janet Mabuza and Benton Otieno and Seth Apollo and Boitumelo Matshediso and Aoyi Ochieng",
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Investigating the synergy of integrated anaerobic digestion and photodegradation using hybrid photocatalyst for molasses wastewater treatment. / Mabuza, Janet; Otieno, Benton; Apollo, Seth; Matshediso, Boitumelo; Ochieng, Aoyi.

In: Euro-Mediterranean Journal for Environmental Integration, Vol. 2, 2017.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Investigating the synergy of integrated anaerobic digestion and photodegradation using hybrid photocatalyst for molasses wastewater treatment

AU - Mabuza, Janet

AU - Otieno, Benton

AU - Apollo, Seth

AU - Matshediso, Boitumelo

AU - Ochieng, Aoyi

PY - 2017

Y1 - 2017

N2 - Anaerobic digestion (AD) can remove the high organic load of molasses wastewater (MWW), but is ineffective in removing the characteristic dark brown colour caused by biorecalcitrant melanoidin. Ultraviolet (UV) photodegradation, can mineralise the biorecalcitrants leading to complete colour removal, but with a high-energy input and low organic load removal. This study investigated the plausibility of integrating the two processes for organic load and colour reductions. Desk scale AD and photodegradation processes were carried out in batch reactors. A hybrid photocatalyst consisting of titanium dioxide (TiO2) and zinc oxide (ZnO) was used for photocatalytic degradation. Biodegradation at thermophilic conditions in the bioreactor achieved high total organic carbon (TOC) and chemical oxygen demand (COD) reductions of 80 and 90%, respectively, but with an increased colour intensity. Contrastingly, UV photodegradation achieved a high colour reduction of 92% with an insignificant 6% TOC reduction, after 30 min of irradiation. During photodegradation, the mineralisation of the biorecalcitrant organic compounds led to the colour disappearance. The energy required for the TOC reduction was 40-fold higher than that required for the colour reduction in the same irradiation period, suggesting that the UV process was only suitable for colour reduction. Therefore, there is a possible synergy when the two processes are integrated, with AD preceding UV, where AD removes the high COD/TOC while UV removes the recalcitrant colour at a reduced cost.

AB - Anaerobic digestion (AD) can remove the high organic load of molasses wastewater (MWW), but is ineffective in removing the characteristic dark brown colour caused by biorecalcitrant melanoidin. Ultraviolet (UV) photodegradation, can mineralise the biorecalcitrants leading to complete colour removal, but with a high-energy input and low organic load removal. This study investigated the plausibility of integrating the two processes for organic load and colour reductions. Desk scale AD and photodegradation processes were carried out in batch reactors. A hybrid photocatalyst consisting of titanium dioxide (TiO2) and zinc oxide (ZnO) was used for photocatalytic degradation. Biodegradation at thermophilic conditions in the bioreactor achieved high total organic carbon (TOC) and chemical oxygen demand (COD) reductions of 80 and 90%, respectively, but with an increased colour intensity. Contrastingly, UV photodegradation achieved a high colour reduction of 92% with an insignificant 6% TOC reduction, after 30 min of irradiation. During photodegradation, the mineralisation of the biorecalcitrant organic compounds led to the colour disappearance. The energy required for the TOC reduction was 40-fold higher than that required for the colour reduction in the same irradiation period, suggesting that the UV process was only suitable for colour reduction. Therefore, there is a possible synergy when the two processes are integrated, with AD preceding UV, where AD removes the high COD/TOC while UV removes the recalcitrant colour at a reduced cost.

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