High-speed video images of helium inductively coupled plasmas for mass spectrometry

Lisa A. Iacone, Michael G. Minnich, Wellington R.L. Masamba, Sang-Ho Nam, Akbar Montaser, Robert G. Michel

Research output: Contribution to journalArticle

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Abstract

High-speed video images of helium inductively coupled plasmas (He ICPs) were obtained at a rate of 1000 frames/s under conditions suitable for mass spectrometry (MS). These experiments established, for the first time, that the He ICP is a rotating discharge at the forward powers (500–1000 W) used for He ICPMS. The rotational frequency of the He ICP ranged from 80 to 250 Hz, depending on the forward power and whether analyte was introduced. When not coupled to the mass spectrometer, the rotational frequency of the He ICP decreased slightly as the forward power was increased. Coupling of the plasma to the mass spectrometer resulted in enhanced plasma oscillations. The implications of these variations on the sensitivity and precision of analytical measurements are discussed. Results are contrasted with data obtained for the Ar ICP.
Original languageEnglish
Pages (from-to)1919-1928
Number of pages10
JournalSpectrochimica Acta, Part B: Atomic Spectroscopy
Volume54
Issue number13
DOIs
Publication statusPublished - 1999

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Helium
Inductively coupled plasma
Mass spectrometers
mass spectrometers
Mass spectrometry
mass spectroscopy
helium
high speed
Plasma oscillations
plasma oscillations
Plasmas
sensitivity
Experiments

Cite this

Iacone, Lisa A. ; Minnich, Michael G. ; Masamba, Wellington R.L. ; Nam, Sang-Ho ; Montaser, Akbar ; Michel, Robert G. / High-speed video images of helium inductively coupled plasmas for mass spectrometry. In: Spectrochimica Acta, Part B: Atomic Spectroscopy. 1999 ; Vol. 54, No. 13. pp. 1919-1928.
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High-speed video images of helium inductively coupled plasmas for mass spectrometry. / Iacone, Lisa A.; Minnich, Michael G.; Masamba, Wellington R.L.; Nam, Sang-Ho; Montaser, Akbar; Michel, Robert G.

In: Spectrochimica Acta, Part B: Atomic Spectroscopy, Vol. 54, No. 13, 1999, p. 1919-1928.

Research output: Contribution to journalArticle

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AU - Iacone, Lisa A.

AU - Minnich, Michael G.

AU - Masamba, Wellington R.L.

AU - Nam, Sang-Ho

AU - Montaser, Akbar

AU - Michel, Robert G.

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AB - High-speed video images of helium inductively coupled plasmas (He ICPs) were obtained at a rate of 1000 frames/s under conditions suitable for mass spectrometry (MS). These experiments established, for the first time, that the He ICP is a rotating discharge at the forward powers (500–1000 W) used for He ICPMS. The rotational frequency of the He ICP ranged from 80 to 250 Hz, depending on the forward power and whether analyte was introduced. When not coupled to the mass spectrometer, the rotational frequency of the He ICP decreased slightly as the forward power was increased. Coupling of the plasma to the mass spectrometer resulted in enhanced plasma oscillations. The implications of these variations on the sensitivity and precision of analytical measurements are discussed. Results are contrasted with data obtained for the Ar ICP.

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