Effects of salinity on solute and ion transport in quasi-structural unstable sodic soil in a semi-arid environment in botswana

Simulations using mixed ions of sodium(Na+) and calcium(Ca2+)

Otlogetswe Totolo, Oagile Dikinya

    Research output: Contribution to journalArticle

    Abstract

    Sodium (Na) and calcium (Ca) ions are the most common ions on the exchange complex in arid and semi-arid soils. The paper examines the effects of the composition of mixed Ca and Na ions in solution on the Na-Ca exchange behaviour and solute transport of an agricultural sodic soil. Permeability index (K/Ko) was used a measure of solute transport. Generally K/Ko was found to decrease with increasing sodium adsorption ratio (SAR) and decreasing electrolyte concentration attributed to mechanisms of swelling and dispersion. In the exchange behviour a strong preference for Ca2+ ions than Na+ ions in the exchange complex was observed. Combined with breakthrough curves obtained for the various solutions these measurements provide insights into the progressive passage of the exchange front and associated structural changes through the soil columns. Measured pHs of the solution were found to remain essentially constant during leaching while the electrical conductivity decreased with decreasing electrolyte concentration. Further elucidation of SAR effects of K/Ko were evaluated at the critical threshold concentration and turbidity concentration at SAR 15. However the results revealed structural breakdown of the pore matrix system as evidenced by decreased permeability during leaching with decreasing solution concentration at SAR 15. The reductions in K/Ko were likely to be caused by partial blocking of pores by dispersed clay particles, as evidenced by the appearance of suspended clay particles in the effluent during leaching.

    Original languageEnglish
    Pages (from-to)215-226
    Number of pages12
    JournalInternational Journal of Applied Environmental Sciences
    Volume5
    Issue number2
    Publication statusPublished - 2010

    Fingerprint

    sodic soil
    arid environment
    solute
    calcium
    sodium
    salinity
    ion
    adsorption
    simulation
    leaching
    solute transport
    electrolyte
    permeability
    clay
    breakthrough curve
    soil column
    agricultural soil
    structural change
    swelling
    electrical conductivity

    All Science Journal Classification (ASJC) codes

    • Environmental Science(all)

    Cite this

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    title = "Effects of salinity on solute and ion transport in quasi-structural unstable sodic soil in a semi-arid environment in botswana: Simulations using mixed ions of sodium(Na+) and calcium(Ca2+)",
    abstract = "Sodium (Na) and calcium (Ca) ions are the most common ions on the exchange complex in arid and semi-arid soils. The paper examines the effects of the composition of mixed Ca and Na ions in solution on the Na-Ca exchange behaviour and solute transport of an agricultural sodic soil. Permeability index (K/Ko) was used a measure of solute transport. Generally K/Ko was found to decrease with increasing sodium adsorption ratio (SAR) and decreasing electrolyte concentration attributed to mechanisms of swelling and dispersion. In the exchange behviour a strong preference for Ca2+ ions than Na+ ions in the exchange complex was observed. Combined with breakthrough curves obtained for the various solutions these measurements provide insights into the progressive passage of the exchange front and associated structural changes through the soil columns. Measured pHs of the solution were found to remain essentially constant during leaching while the electrical conductivity decreased with decreasing electrolyte concentration. Further elucidation of SAR effects of K/Ko were evaluated at the critical threshold concentration and turbidity concentration at SAR 15. However the results revealed structural breakdown of the pore matrix system as evidenced by decreased permeability during leaching with decreasing solution concentration at SAR 15. The reductions in K/Ko were likely to be caused by partial blocking of pores by dispersed clay particles, as evidenced by the appearance of suspended clay particles in the effluent during leaching.",
    author = "Otlogetswe Totolo and Oagile Dikinya",
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    TY - JOUR

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    AU - Dikinya, Oagile

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    AB - Sodium (Na) and calcium (Ca) ions are the most common ions on the exchange complex in arid and semi-arid soils. The paper examines the effects of the composition of mixed Ca and Na ions in solution on the Na-Ca exchange behaviour and solute transport of an agricultural sodic soil. Permeability index (K/Ko) was used a measure of solute transport. Generally K/Ko was found to decrease with increasing sodium adsorption ratio (SAR) and decreasing electrolyte concentration attributed to mechanisms of swelling and dispersion. In the exchange behviour a strong preference for Ca2+ ions than Na+ ions in the exchange complex was observed. Combined with breakthrough curves obtained for the various solutions these measurements provide insights into the progressive passage of the exchange front and associated structural changes through the soil columns. Measured pHs of the solution were found to remain essentially constant during leaching while the electrical conductivity decreased with decreasing electrolyte concentration. Further elucidation of SAR effects of K/Ko were evaluated at the critical threshold concentration and turbidity concentration at SAR 15. However the results revealed structural breakdown of the pore matrix system as evidenced by decreased permeability during leaching with decreasing solution concentration at SAR 15. The reductions in K/Ko were likely to be caused by partial blocking of pores by dispersed clay particles, as evidenced by the appearance of suspended clay particles in the effluent during leaching.

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